Lithium-Aluminum Contacts for Organic Light-Emitting Devices

Organic light-emitting devices have been prepared with multilayer Al-Li-Al cathodes in an ultrahigh vacuum molecular beam deposition system. The optimum device characteristics are obtained when there is a single Al layer separating the Li layer from the organic materials. Ab initio molecular dynamics calculations of the Al-Li interaction clarify the role of Al as a blocking layer to Li diffusion into the organic films as well as the behavior of the device when the thickness of this Al interfacial layer is changed.